Here you go, this will help to see if your smart meter will link:
https://smartmetercheck.citizensadvice.org.uk/
You can also use one of the numerous apps like Hugo, Bright or Loop and if you can get 30 min readings you should be fine.
You can get gas with Octopus, it’ll either be the variable rate (which is the same everywhere), or you could go to gas tracker, which tracks the next day wholesale gas price and it fluctuates daily up to a cap octopus have set - but as the cap for that is now 22p, come winter it won’t look very good - at the moment it’s tracking at about 6p/kWh for gas so well below the government price cap, but when demand increases, it won’t be lower than the 22p (although the government support will bring it down to 18p).
Depending on usage, you only need to drive about 5000 miles for it to be beneficial, less if you load shift appliances too.
Quick maths based on my own usage to show this point.
So I’m putting 28kwh into the car at 7.5p twice a week at night which is £2.10. If I I was SVR (@34p) that is £9.52.
I use 8 kWh per day in the house - 2kwh of these are washing machine and dishwasher - I put these on during the cheap rate so cost £0.15, if it was SVR it would be £0.68.
Then I use 6kwh at 40p which is £2.40, if it was SVR it would be £2.04.
So total cost usage for me is £2.10+£0.15+£2.40 = £4.65 per day (I charge) for 36kwh which averages at 12.66p/kwh.
If it was SVR at the exact same usage it’s £12.24 for 36kwh which obviously averages 34p/kWh.
Now if I average this over the week, I would use 104 kWh 2 days at (36kwh and 5 days at 8 kWh) if that’s the SVR (28p) it would be £37.44.
With octopus go it’s (4.65*2)+(2.55*5) = £22.05 which is an average rate of 21.2p.
So total savings over the year of £800.28 - based on the current SVR rate.
Obviously it depends on your own usage, but if you want to try my spreadsheet calculator to see how it would work out, you can download it freely at the below link. Or, if you need a hand you can answer a quick few questions and I can plug it in my end for you!

let me know if you need a hand with it!
Time of Use Tariff vs SVR July 2022 Prime V4.1 copy 2.xlsx